Power and thermal characterization of a lithium-ion battery pack for hybrid-electric vehicles

A 1D electrochemical, lumped thermal model is used to explore pulse power limitations and thermal behavior of a 6 Ah, 72 cell, 276 V nominal i-ion hybrid-electric vehicle (HEV) battery pack. Depleted/saturated active material Li surface concentrations in the negative/positive electrodes onsistently cause end of high-rate (∼25 C) pulse discharge at the 2.7 V cell−1 minimum limit, indicating solid-state diffusion is the limiting echanism. The 3.9 V cell−1 maximum limit, meant to protect the negative electrode from lithium deposition side reaction during charge, is overly onservative for high-rate (∼15 C) pulse charges initiated from states-of-charge (SOCs) less than 100%. Two-second maximum pulse charge rate rom the 50% SOC initial condition can be increased by as much as 50% without risk of lithium deposition. Controlled to minimum/maximum oltage limits, the pack meets partnership for next generation vehicles (PNGV) power assist mode pulse power goals (at operating temperatures 16 ◦C), but falls short of the available energy goal. In a vehicle simulation, the pack generates heat at a 320 W rate on a US06 driving cycle at 25 ◦C, with more heat generated at lower temperatures. ess aggressive FUDS and HWFET cycles generate 6–12 times less heat. Contact resistance ohmic heating dominates all other mechanisms, ollowed by electrolyte phase ohmic heating. Reaction and electronic phase ohmic heats are negligible. A convective heat transfer coefficient of = 10.1 W m−2 K−1 maintains cell temperature at or below the 52 ◦C PNGV operating limit under aggressive US06 driving. 2006 Elsevier B.V. All rights reserved.